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I think it might actually make it worse.
You are less likely to see a reflection in the glass when you can see through it - if more light is coming from outside then in (think looking inside a dark house when it's bright outside - if the lights are off, you won't see anything, just your reflection. If the lights are on, it's easier to see in).
Once you paint it, there will be no way for it to see through the glass, and while it may not always see a reflection, it will probably see one more often then if the glass was bare.
You are less likely to see a reflection in the glass when you can see through it - if more light is coming from outside then in (think looking inside a dark house when it's bright outside - if the lights are off, you won't see anything, just your reflection. If the lights are on, it's easier to see in).
Once you paint it, there will be no way for it to see through the glass, and while it may not always see a reflection, it will probably see one more often then if the glass was bare.