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Depends,

What substrate do you have ? Is the filter available ? What do you plan to do after you add water ?

My suggestion is to post in a subforum suitable for your location and ask for plant donations. Most of us have excess cuts that will happily donate or sell very cheap.
 

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if adding water, dechlorinate 24 hours before adding the SafeStart.

I filled my 50 gallon yesterday and dechlorinated.
I dumped in SafeStart about an hour before heading to the LFS today. Bought 6 angels and so far they are happy as clams. I got a nitrite rise after about 4 hours so they are working.
 
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