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The Emperor is off gassing any co2 your getiing into the water from your diy setup. If you really want to get rid of it buy a pressurized system. It wont be necessary to get a canister filter but that would be your next move. Also your Emperor probly is not creating optimal water ciirculation either. I have a XP3 on a 55g and feel it is barely adequite but it is a low light tank. If it were like yours it would deffinantly be inadequite.

Either take out one bulb over the tank or get ready to spend some cash on a proper set up.
 
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