No, you will not have to change your photoperiod. It's actually a good idea to not make too many changes at once on a stable tank. That way, if you get results you're not happy with, you know what changes led to those results which can better help you make adjustments.
Having more CO2 than the plants can use due to lower lighting is not a problem. The problem most people run into is the opposite: not having enough CO2 due to increased lighting.
So you can add your CO2 and leave your lighting as it is. Once you feel comfortable, you can increase your photoperiod a little to see how that affects things. If all is going well, you can increase your photoperiod even more. Keep doing this until you get the photoperiod you want or you run into problems. Either way, you'll be able to track what changes created what affects which makes it easier for you to know what other changes you need to make if things go wrong.
Having more CO2 than the plants can use due to lower lighting is not a problem. The problem most people run into is the opposite: not having enough CO2 due to increased lighting.
So you can add your CO2 and leave your lighting as it is. Once you feel comfortable, you can increase your photoperiod a little to see how that affects things. If all is going well, you can increase your photoperiod even more. Keep doing this until you get the photoperiod you want or you run into problems. Either way, you'll be able to track what changes created what affects which makes it easier for you to know what other changes you need to make if things go wrong.