I wouldn't use baking soda to buffer the water. It contains to many impurities. Also, if you mess around with baking soda to buffer the water, you can't use that pH/KH chart to determine your CO2, as it won't be accurate. Try Seachem Alkaline Buffer and Equilibrium if you want to buffer the water. If the parameter is not that extreme, I would not play with the pH/KH.