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Wow, those are really cool looking. If you are unsure about using them, just stick them in a bucket and wait a few weeks. Test the water the first day, a week or so in, and after that, if you get a significant change, you may want to reevaluate. I have used vinegar and muiratic acid in the past. On some occasions the vinegar has been too week and I had hardness issues and the acid has been too strong and I found I had very little hardness with them. This, to me, is more telling.
 
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