I read a book by Walstad regarding the experiment comparing ammonium ion and nitrate. According to the result most aquatic plants utilised ammonium more readily than nitrate. The only question regarding the experiment is that she use 2ppm instead of higher level of ammonium.
I believe when ammonia dissolve in water it readily accept proton to form Ammonium hydroxide, which is basic. After that the ammonium hydroxide may react with acidic compound to form ammonium salts which also soluble in water. In other words, in lower pH water more ammonia form ammonium in water which are relatively harmless.
NH3 + H2O -> NH4+ + OH-
In CO2 enrich water
2NH3+H2O+CO2 -> (NH4)2CO3
Since we normally dose around 20-30ppm of co2 most ammonia will react with carbonic acid to form ammonium ion.
However when water pH is high ammonium ammonia equilibrium will shift more to other left. In other words more ammonia will be present in water instead of ammonium.
sometimes I suspect plants may not dead due to high ammonia level,in acidic water it may in other way round. Plants death cause increase in ammonia. High pH water increase toxicity of ammonia in water to fish. However it still remain undecided whether ammonia molecule in stead of ion are toxic to aquatic plants. I'm still wandering is there any scientific journal covering this topic.
p.s. all my idea are base on logic speculation and may not work the same way in real life. Any one who work in scientific field should devise an experiment and let us know the result.
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