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Can this be done?

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Is there any way to separate substrate? I upgraded from a 10 gallon to 20 and used Miracle grow with my old eco complete as a cap. Now I want to go back to my 10 and want to just use the eco complete. If not can I just scoop it all and mix it? will it separate on it's own and become capped or am I doomed to buy new substrate?
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