The cases where Ca++ limitation can potential occurs: PURE RO heavy water change users who do not add Gh booster back and folks that also do not dose any GH booster and also have a salt based water softener or resins..
In either case, adding a little bit of GH booster will quickly rule this issue out.
You are not dosing correctly if it is actually a Ca++ issues, those pics look just like CO2 deficiencies to me.