I'm no expert but i don't think it will work can't remember why something about expansion rates I think also silicone will not bond very well to acrylic so silicone is out.
try a local glass guy sometimes they will give you small pieces like that free or next to free especially since you could use a scratched piece
try a local glass guy sometimes they will give you small pieces like that free or next to free especially since you could use a scratched piece